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- W2007353071 abstract "Chain entanglement in poly (methyl methacrylate), polystyrene, poly poly(N-phenylmaleimide), poly(methyl methacrylate-stat-styrene), poly(methyl methacrylate-stat-N-phenylmaleimide) and poly(methyl methacrylate-state-styrene-stat-N-phenylmaleimide) is studied in the melt by dynamic viscoelastic spectroscopy. It is shown that the plateau modulus is equal to the storage modulus at the minimum of loss tangent. The plateau modulus and the entanglement molecular weight are found to obey the geometric mean relationship with respect to composition, i.e. log G0N = ∑vj log G0Nj and log Me = ∑vj log Mej, where G0N is the plateau modulus, Me the molecular weight between entanglement points, vj the volume fraction of comonomer j, G0Nj the plateau modulus for the homopolymer of j and Mej the entanglement molecular weight for the homopolymer of j. The G0N and Me of homopolymers and copolymers may also be predicted by group additivity method." @default.
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- W2007353071 date "1992-01-01" @default.
- W2007353071 modified "2023-10-12" @default.
- W2007353071 title "Chain entanglement in homopolymers, copolymers and terpolymers of methyl methacrylate, styrene and N-phenylmaleimide" @default.
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- W2007353071 doi "https://doi.org/10.1016/0032-3861(92)90727-e" @default.
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