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- W2007359580 abstract "Abstract Effect of Pt particle size on the catalytic activity of complete ethylene oxidation in the temperature range of 25–220 °C in fuel-lean conditions is investigated. Carbon black is used as a support for platinum nanoparticles of well-defined average sizes between 1.5 and 6.3 nm. The results demonstrate that ethylene oxidation on Pt/C is strongly size sensitive reaction. Thus, the smallest Pt/C-4 nanoparticles (1.5 ± 0.5 nm) exhibit much higher catalytic activity toward ethylene oxidation reaching 50% conversion at 88 °C compared to 164 °C for the largest Pt/C-1 (6.3 ± 0.5 nm) nanocatalysts. XPS shows that particle size decrease results in noticeable binding energy increase and Pt4f peak broadenings. This indicates that the electronic effect induced by small Pt nanoparticles might play a role in the observed increase in their activity toward C 2 H 4 oxidation." @default.
- W2007359580 created "2016-06-24" @default.
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- W2007359580 date "2013-08-01" @default.
- W2007359580 modified "2023-10-14" @default.
- W2007359580 title "Particle size effect on catalytic activity of carbon-supported Pt nanoparticles for complete ethylene oxidation" @default.
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- W2007359580 doi "https://doi.org/10.1016/j.apcata.2013.05.027" @default.
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