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- W2007363352 abstract "This report examines the organization properties of new fluorescent DNA-lipids, either alone in water or in interaction with 1-octyl-β-d-glucopyranoside micelles or egg phosphatidylcholine vesicles. We first describe the design and the syntheses of the conjugates. Then, we use UV−Vis absorption, steady-state fluorescence emission, electron microscopy, and fluorescence correlation spectroscopy after two-photon excitation to show that these DNA-lipids form spherical micelles in aqueous solution and incorporate much better in micelles than in vesicles. We also investigate the significance of the lipophilic chains of these DNA-lipids on the melting behavior of the double-stranded hybrids: in water melting curves are broadened whereas in amphiphilic assemblies duplexes melt as the unconjugated controls. This work is expected to be useful for improving the rational design of antisense medicines." @default.
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- W2007363352 date "2004-04-28" @default.
- W2007363352 modified "2023-09-30" @default.
- W2007363352 title "Micelles of Lipid−Oligonucleotide Conjugates: Implications for Membrane Anchoring and Base Pairing" @default.
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- W2007363352 doi "https://doi.org/10.1021/jp031188m" @default.
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