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- W2007364083 abstract "The UV absorption spectrum of relatively dense Zn vapour is measured and the absolute absorption coefficient in the far blue wing of the self-broadened Zn (41P1 − 41S0) 213.8 nm resonance line, associated with the (11u ← X10g+) molecular transition, is quantitatively analysed for the first time. The satellite band, resulting from transitions occurring in the region of the potential barrier in the excited 11u state, is observed at about 1600 cm−1 from the line centre and utilized for probing available theoretical interaction data via quantum simulations of this spectrum. A comparison between the simulated band and experimental one shows that the former in any case is considerably blue shifted, indicating that the theoretical findings concerning the height of the potential barrier in the excited state involved are overestimated. The corrected height and position of this barrier, yielding very good agreement between the simulated and experimental band positions, are established to be (1470 ± 50) cm−1 and (3.8 ± 0.2) A, respectively. The error bounds are here determined predominantly by the ground-state potential uncertainty, which still remains an open question. The general behaviour of the dipole transition moment function for the considered transition is also briefly discussed." @default.
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- W2007364083 date "2007-01-10" @default.
- W2007364083 modified "2023-10-04" @default.
- W2007364083 title "The blue satellite of the Zn (41P1− 41S0) 213.8 nm resonance line: test of the potential barrier in the excited11u(41P1) state of the Zn dimer" @default.
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- W2007364083 doi "https://doi.org/10.1088/0953-4075/40/2/009" @default.
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