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- W2007365329 abstract "Abstract Thermolysis of Ru(IMes)(dppp)(CO)H 2 ( 1 , IMes=1,3‐dimesityl‐1,3‐dihydro‐2 H ‐imidazol‐2‐ylidene; dppp=Ph 2 PCH 2 CH 2 CH 2 PPh 2 ) in the presence of trimethylvinylsilane yields Ru(IMes')(dppp)(CO)H ( 2 ) resulting from intramolecular ArCH 2 –H CH bond activation of the N ‐heterocyclic carbene ligand. The structures of 1 and 2 have been established by X‐ray crystallography. Treatment of Ru(IMes)(arphos)(CO)H 2 ( 3 , arphos=Ph 2 AsCH 2 CH 2 PPh 2 ) with CH 2 CHSiMe 3 at 85 °C produces a mixture of three CH activated products 4a – c . The CH activated complexes 2 and 4a – c reform their dihydride precursors upon heating under hydrogen." @default.
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- W2007365329 date "2003-09-01" @default.
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- W2007365329 title "Reversible CH Bond Activation Reactions of theN-Heterocyclic Carbene Ligands in Ru(Ph2PCH2CH2CH2PPh2)(IMes)(CO)H2 and Ru(Ph2AsCH2CH2PPh2)(IMes)(CO)H2 (IMes=1,3-Dimesityl-1,3-dihydro-2H-imidazol-2-ylidene)" @default.
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- W2007365329 doi "https://doi.org/10.1002/adsc.200303074" @default.
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