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• W2007367776 abstract "Abstract The crystal structures and the magnetic properties of a pentanuclear (1) and a nonanuclear (2) Ni(II) clusters are described. In the former, crystallizing in the cubic I23 space group, the Ni(II) assembly is composed of a regular tetrahedral geometry of four metal ions centered on the fifth. The nonanuclear cluster crystallizes in the hexagonal crystallographic system -R3 space group - the Ni(II) assembly is composed of two regular tetrahedra, like that of the pentanuclear cluster, sharing a common apex. All metal ions in either cluster are six-coordinate. Variable-temperature magnetic susceptibility data show antiferromagnetic interactions for both clusters. Moreover, magnetization data are in line with uneven intermediate-spin ground states [S=1, S=2] and [S=2, S=3] for 1 and 2, respectively. A comparison of both the symmetry and the spin ground state of 1 to those of lower-symmetry pentanuclear Ni(II) clusters, reveals that the ground-state spin value increases with the cluster symmetry." @default.
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• W2007367776 date "1999-09-01" @default.
• W2007367776 modified "2023-10-16" @default.
• W2007367776 title "The Case of Symmetry-Dependent Ground-State Spin Value in Ni(II) Clusters of High-Nuclearity. Crystal Structure and Magnetic Properties of a Pentanuclear and a Nonanuclear Ni(II) Clusters" @default.
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• W2007367776 doi "https://doi.org/10.1080/10587259908028888" @default.
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