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- W2007367989 abstract "6,13-Dihydro-6,13-ethanopentacene-15,16-dione is a soluble precursor of pentacene, which can be converted into pentacene by irradiation in the solid-state. Its photoconversion process in spin-coated films was monitored by UV-visible absorption and IR spectroscopy. A small amount of high-boiling-point additives in the chloroform spin-coating solution promoted photoconversion to obtain high quality films suitable for FETs. The FET mobilities showed a correlation with the additives' boiling points and dissolution abilities, indicating that the retainment of a semidry state during photoconversion is essential to the complete photoconversion. Photoirradiation conditions (irradiation intensity, duration and substrate temperature) were optimized to achieve a field-effect mobility of 0.86 cm2 V−1 s−1, comparable to the performance of vacuum-deposited pentacene films. The prepared films have a partially crystalline morphology different from that of vacuum-deposited films. The high FET mobility of the photoconverted film is attributed to continuously connected grain boundaries arising from partial crystallinity." @default.
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- W2007367989 date "2013-01-01" @default.
- W2007367989 modified "2023-09-26" @default.
- W2007367989 title "Characterization and field-effect transistor performance of printed pentacene films prepared by photoconversion of a soluble precursor" @default.
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- W2007367989 doi "https://doi.org/10.1039/c3tc31083c" @default.
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