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- W2007372277 abstract "A series of Ni(OEtHex)2/phosphine/Et2AlCl systems were used as cycloisomerization catalysts of various 1,6-heptadienes. The best results were obtained with the catalytic system using triphenylphosphine as a ligand. The cycloisomerization with this system afforded the corresponding methyl(methylene)cyclopentane derivatives with high selectivity (40–99%) and in good overall yields of the cyclopentane derivatives (90–96%). The cycloisomerization proceeded also with other derivatives possessing 1,6-diene moiety giving the corresponding methyl(alkenyl)cyclopentane derivatives in good yields (33–90%)." @default.
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- W2007372277 date "2007-09-01" @default.
- W2007372277 modified "2023-10-12" @default.
- W2007372277 title "Ni(ethylhexanoate)2/nligand/Et2AlCl catalyzed cycloisomerization of 1,6-heptadienes to cyclopentane derivatives" @default.
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- W2007372277 doi "https://doi.org/10.1016/j.molcata.2007.04.032" @default.
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