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- W2007376083 abstract "Abstract The dialkylamides of tin react with ironpentacarbonyl to form carbene complexes. With Me 2 Sn(NMe 2 ) 2 and Sn(NMe 2 ) 4 yellow dicarbene complexes are formed by addition of two SnN bonds to adjacent carbonyl groups. The two carbenoid systems on the central atom are parts of a chelate ligand connected by an OSnO bridge. Using [Sn(NMe 2 ) 2 ] 2 , a red monomeric compound (CO) 3 Fe(CONMe 2 ) 2 Sn containing the same cyclic structural unit can be isolated. The free activation enthalpy of rotation about the C(carbene)N bond in the tin (IV) dicarbene complexes was found to be 16.5 kcal mol -1 ." @default.
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- W2007376083 date "1976-11-01" @default.
- W2007376083 modified "2023-09-26" @default.
- W2007376083 title "Mono- und dicarbenkomplexe durch reaktion von pentacarbonyleisen mit einigen dialkylamiden des zwei- und vierwertigen zinns" @default.
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- W2007376083 doi "https://doi.org/10.1016/s0022-328x(00)98053-7" @default.
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