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- W2007378009 abstract "Starting from the optically active PH phospholanes diopholane HPDph and tarpholane HPTph, the phosphido bridged complexes 1–6 were prepared and characterized. Complexes 2 and 3 exist as two diastereomers differing only in the configuration of the Mo atom. The temperature dependence of the 1H NMR spectra of these complexes reveals an intramolecular fluxional process. The rhodium complexes 4–6 were used as enantioselective catalysts in the hydrogenation of α-ethylstyrene and in the hydrosilylation of acetophenone with diphenylsilane. Ausgehend von den optisch aktiven PH-Phospholanen Dipholan HPDph und Tarpholan HPTph wurden die Phosphido-verbrückten Komplexe 1–6 synthetisiert und charakterisiert. Die Komplexe 2 und 3 liegen als Diastereomere vor, die sich nur in der Konfiguration des Mo-Atoms unterscheiden. Die Temperaturabhängigkeit der 1H-NMR-Spektren dieser Komplexe zeigt einen intramolekularen fluktuierenden Prozeß. Die Rhodiumkomplexe 4–6 wurden als enantioselektive Katalysatoren in die Hydrierung von α-Ethylstyrol und in die Hydrosilylierung von Acetophenon mit Diphenylsilan eingesetzt." @default.
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- W2007378009 date "1990-09-01" @default.
- W2007378009 modified "2023-09-27" @default.
- W2007378009 title "Optisch aktive übergangsmetallkomplexe XCIX. Optische aktive phosphido-verbrückte molybdän-, rhodium- und eisenkomplexe" @default.
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- W2007378009 doi "https://doi.org/10.1016/0022-328x(90)85171-t" @default.
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