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- W2007379670 abstract "The synthesis and spectroscopic characterization of a series of luminescent platinum meso-tetrakis{3,5-di[(N-carbazyl)n-alkyloxyphenyl]}porphyrin (Pt-8Cn-TPP, n-alkyl = (CH2)n, n = 4, 6, and 8) are presented. The protonated platinum porphyrins ([Pt-8Cn-TPPH8]8+) were assembled with mesoporous silica MCM-48 resulting in the assembly materials [Pt-8Cn-TPPH8]8+/MCM-48. The luminescence of [Pt-8Cn-TPPH8]8+/MCM-48 can be extremely quenched by molecular oxygen with very high sensitivity (I0/I100 > 5000) and rapid response time (0.04 s) suggesting that the [Pt-8Cn-TPPH8]8+/MCM-48 system can be employed to develop high performance oxygen sensors. Among this assembly system, [Pt-8C8-TPPH8]8+/MCM-48 exhibits the highest sensitivity. Even if the concentration of oxygen is 0.1%, the luminescence intensity of [Pt-8C8-TPPH8]8+/MCM-48 can be quenched by 86%." @default.
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- W2007379670 date "2006-05-11" @default.
- W2007379670 modified "2023-10-15" @default.
- W2007379670 title "Synthesis and Assembly with Mesoporous Silica MCM-48 of Platinum(II) Porphyrin Complexes Bearing Carbazyl Groups: Spectroscopic and Oxygen Sensing Properties" @default.
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- W2007379670 doi "https://doi.org/10.1021/ic060354c" @default.
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