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- W2007396984 abstract "In this paper, the resistance switching effect has been studied in NaNbO3:Mn crystals. Samples were rejuvenated in ambient air, below and above antiferroelectric phase transition. Dielectric spectroscopy has exhibited weak dispersion. The influence of annealing on the electronic structure has been determined with the use of X-ray photoelectron spectroscopy. Na2s, Nb3d, O1s, and Mn2p lines of the aged as-grown crystal and the rejuvenated samples spectra have been analyzed. Nb4+ states observed in the samples point to the presence of oxygen vacancies in the surface layer. Na ions migrate toward the surface due to rejuvenation. Switching from an insulator high-resistance state to a semiconductor medium resistance and finally to a metallic-type low-resistance state has been observed. The results are discussed within the framework of the extended defects model. We propose that the aliovalent Mn2+ dopant ions stabilize the oxygen vacancies and enable the resistive switching." @default.
- W2007396984 created "2016-06-24" @default.
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- W2007396984 date "2014-10-13" @default.
- W2007396984 modified "2023-09-27" @default.
- W2007396984 title "Resistance switching in rejuvenated NaNbO<sub>3</sub>:Mn crystals" @default.
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- W2007396984 doi "https://doi.org/10.1080/01411594.2014.953518" @default.
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