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- W2007403191 abstract "Abstract Paracrystalline array of defect clusters ca. five times the lattice spacing of the average Co 3− δ O 4 spinel structure occurred more or less in a relaxed manner when the sintered Co 1− x O polycrystals were air-quenched below the Co 1− x O/Co 3− δ O 4 transition temperature to activate oxy-precipitation of cube-like Co 3− δ O 4 at dislocations. The same paracrystalline spacing was obtained for Co 3− δ O 4 when formed via oxidizing/sintering the Co 1− x O powders at 800°C in air, suggesting a nearly constant δ value for Co 3− δ O 4 in the T – P O 2 conditions encountered. The extra cobalt vacancies and Co 3+ interstitials, as a result of δ value, may form additional 4:1-derived defect clusters for further paracrystalline distribution in the spinel lattice. The nanosize defect clusters self-assembled by columbic interactions and lattice relaxation in ionic crystal may have potential applications as step-wise sensor of oxygen partial pressure at high temperatures." @default.
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- W2007403191 date "2004-01-01" @default.
- W2007403191 modified "2023-09-26" @default.
- W2007403191 title "Co3−δO4 paracrystal: 3D assembly of nanosize defect clusters in spinel lattice" @default.
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- W2007403191 doi "https://doi.org/10.1016/s0022-4596(03)00324-4" @default.
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