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- W2007403775 abstract "The crystal structure of [Cu(NCS)(C 12 H 8 N 2 ) 2 ]ClO 4 , containing a five-coordinate copper(II) atom with a distorted trigonal-bipyramidal [Cu II N 5 ] core, is reported. The Cu-NCS distance is 2.005 (5) A with Cu bonded to the N-atom end of the isothiocyanate, while the Cu-N distances to the 1,10-phenanthrolines average 2.069 (4) A for the equatorial positions and 2.002 (4) A for the axial positions. The geometry is distorted from trigonal bipyramidal stereochemistry because the N-Cu-N angles of the 1,10-phenanthrolines average only 80.5 (2) o . The axial N and Cu atoms are almost linear with an angle of 174.8 (2) o . The isothiocyanate chain is approximately linear [178.7 (5) o ] and bent at 166.1 (5) o from the Cu atom" @default.
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- W2007403775 date "1994-08-15" @default.
- W2007403775 modified "2023-09-23" @default.
- W2007403775 title "Isothiocyanatobis(1,10-phenanthroline)copper(II) perchlorate, [Cu(NCS)(phen)2]ClO4" @default.
- W2007403775 doi "https://doi.org/10.1107/s0108270194003057" @default.
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