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- W2007404802 abstract "The thermal phase transition behavior of water incorporated in crosslinked polystyrene-divinylbenzene copolymer (PS-DVB) gel packings for liquid chromatography was investigated by differential scanning calorimetry. Free or bulk water, freezable bound or intermediate water, and nonfreezing water were observed for TSKgel Styrene-250 samples, while only free water and nonfreezing water were observed for TSKgel Styrene-60 samples. Freezable bound water and nonfreezing water in these gel samples were considered to be water confined in pores of the polymer gels. A liquid chromatographic method for determination of the amounts of stationary phase water was applied to the characterization of water in the PS-DVB beads in the columns and it was found out that any water in the PS-DVB gels did not function as the stationary phase contrary to the water sorbed in hydrophilic polymer gels; not only freezable bound water but also nonfreezing water in hydrophobic PS-DVB gels are similar to bulk water with respect to the affinity to the solute compounds." @default.
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- W2007404802 date "2003-08-01" @default.
- W2007404802 modified "2023-09-27" @default.
- W2007404802 title "Liquid chromatography and differential scanning calorimetry studies on the states of water in polystyrene–divinylbenzene copolymer gels" @default.
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- W2007404802 doi "https://doi.org/10.1016/s0021-9673(03)01132-4" @default.
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