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• W2007415086 abstract "Reaction of the appropriate R2SnCl2 with the potassium salt of the imidobis(diphenylselenophosphinate-Se,Se′) ligand (1c) in 1:2 stoichiometry yields n-Bu2Sn[{N(SePPh2)2-Se,Se′}2] (2) and Ph2ClSn[N(SePPh2)2-Se,Se′]·H2O (3). The crystal and the molecular structures of both compounds were determined by X-ray diffractometry. The core geometry in compound 2 is a quasi perfect octahedron. Two selenide ligands are coordinated symmetrically to the tin atom forming a spiro-bicyclic NP2Se2SnSe2P2N system [Σ(SeSnSe) = 360°. Both organo substituents are in trans positions [(C′SnC′A) = 180.0(1)°] and they are almost perpendicular to the SnSe4 plane. In derivative 3 only one selenium-based ligand is coordinated asymmetrically to the tin atom and unexpectedly a chlorine atom remains attached to the metal center. The geometry around the tin atom corresponds to a distorted trigonal bipyramid with the Se(1) and Cl atoms at the axial positions." @default.
• W2007415086 created "2016-06-24" @default.
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• W2007415086 date "1997-10-01" @default.
• W2007415086 modified "2023-10-17" @default.
• W2007415086 title "First functionalized diorganotin (IV) derivative containing the imidobis(diphenylselenophosphinate-Se,Se′ ligand. The synthesis and X-ray crystal structures of Bu2Sn[{N(SePPh2)2-Se,Se′}2] and Ph2ClSn[N(SePPh2)2-Se,Se′]·H2O" @default.
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• W2007415086 doi "https://doi.org/10.1016/s0022-328x(97)00340-9" @default.
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