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- W2007459614 abstract "We present a study of the Van Vleck paramagnets ${mathit{A}}_{1mathrm{ensuremath{-}}mathit{x}}$${mathrm{Cr}}_{mathit{x}}$B and ${mathit{A}}_{1mathrm{ensuremath{-}}mathit{x}}$${mathrm{Fe}}_{mathit{x}}$B, where AB is a II-VI semiconductor having the zinc-blende or the wurtzite structure. In cubic zinc-blende hosts the nonlinear magnetization M depends on the orientation of the external magnetic field B with respect to the cubic axes of the crystal. We show that, while for iron M is largest when B is along a cubic axis and a minimum for Bensuremath{parallel}[111], for chromium the anisotropy is reversed and the largest value of M occurs for Bensuremath{parallel}[111]. Expansions of the angular variation of the magnetization in terms of combinations of spherical harmonics invariant under the operations of the symmetry group (${mathit{T}}_{mathit{d}}$ or ${mathit{C}}_{3mathit{v}}$) of the site of the impurity are used to analyze the anisotropy. The magnetic-field dependence of the coefficients in the expansion is investigated. The magnetic susceptibility of ${mathrm{Cr}}^{2+}$ in wurtzite-structure hosts is expected to be particularly large." @default.
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- W2007459614 title "Van Vleck paramagnetism of chromium- and iron-doped II-VI semiconductors" @default.
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- W2007459614 doi "https://doi.org/10.1103/physrevb.48.14127" @default.
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