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- W2007462012 abstract "The trans/cis ratios in butene and hexene products arising from the metathesis of cis- and trans-pent-2-ene have been measured at zero conversion for a series of catalysts of the type W(OAr)4Cl2. With Cis-pent-2-ene, the results for all the catalysts were similar and comparable with those of other workers using different W(VI) catalysts. The trans/cis ratios for reactions of trans-pent-2-ene show a marked dependence on the nature of the OAr ligand attached to the catalyst. Those ligands bearing ortho substituents give rise to a much greater cis selectivity. A possible explanation of this result is given in terms of specific ligand interactions." @default.
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- W2007462012 date "1985-01-01" @default.
- W2007462012 modified "2023-09-25" @default.
- W2007462012 title "Stereochemistry of metathesis catalysed by W(VI) compounds" @default.
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- W2007462012 doi "https://doi.org/10.1016/0304-5102(85)87015-2" @default.
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