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- W2007465960 abstract "The Si-Si bond cleavage reaction of decaisopropylbicyclo[2.2.0]hexasilane with PdCl2(PhCN)2 gave cis- and trans-1,4-dichlorocyclohexasilanes. X-ray crystallography of these products show sterically distorted chair conformations of the Si6 rings. The cis- and trans-cyclohexasilane show rather different absorptions in the UV spectra. By treatment with sodium, both isomers reproduced the bicyclo[2.2.0]hexasilane quantitatively." @default.
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- W2007465960 date "1994-02-01" @default.
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- W2007465960 title "Selective Si-Si Bond Cleavage in Decaisopropylbicyclo[2.2.0]hexasilane. A Route to Sterically Hindered 1,4-Dichlorocyclohexasilanes" @default.
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- W2007465960 doi "https://doi.org/10.1246/cl.1994.221" @default.
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