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- W2007471153 abstract "Abstract The patterns of photochemical and thermal degradation of the additive bis-( p -benzoquinone diazide) methane in films of polyvinyl alcohol have been investigated. In the processes of photolysis at 183–259 K and thermolysis at 322–373 K there is crosslinkage of the macromolecules as a result of insertion 'at the hydroxyl groups of the polymer of the cyclohexadienone carbenes formed on degradation of the diazo compound. The quantum yield of photo-degradation does not depend on temperature and amounts to 4 × 10 −3 . The thermodegradation of the additive is described by a first order kinetic law with the effective rate constant k T = 5 × 10 10 exp (−85·6/RT), sec −1 . The effectiveness of crosslinking at different temperatures is evaluated." @default.
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- W2007471153 date "1986-01-01" @default.
- W2007471153 modified "2023-09-25" @default.
- W2007471153 title "Crosslinking of polyvinyl alcohol macromolecules during photo- and thermo-degradation of bis(p-Benzoquinone diazide) methane" @default.
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- W2007471153 doi "https://doi.org/10.1016/0032-3950(86)90182-6" @default.
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