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• W2007477256 abstract "Reactions of NH32+ di-cations, observed a few microseconds after formation by electron ionisation of ammonia, have been studied in a double-focusing mass spectrometer using techniques of ion translational energy spectroscopy. Fragmentation reactions occuring under unimolecular conditions correspond to predissociation processes, but lack of knowledge about states of NH32+ precludes any definitive interpretation. A partial tentative interpretation, using arguments by analogy with isoelectronic neutral species, is proposed. Almost all collision-induced fragmentations required electron transfer forming NH3+ as an intermediate step, so the non-dissociative electron transfer processes were also studied. The most unexpected collision-induced fragmentation reaction was that which formed H3+ fragment ions." @default.
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• W2007477256 date "1985-12-01" @default.
• W2007477256 modified "2023-10-05" @default.
• W2007477256 title "Delayed predissociation and collision-induced processes of the ammonia di-cation NH32+" @default.
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• W2007477256 doi "https://doi.org/10.1016/0301-0104(85)85013-8" @default.
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