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- W2007481875 abstract "The nuclear magnetic resonance spectra of seven 4,6-disubstituted o-cresols (4,6-dinitro-, 4-nitro-6-bromo-, 4,6-dichloro-, 4,6-dibromo-, 4,6-diiodo-, 4,6-dimethyl-, and α, 4,6-tribromo-o-cresol) have been examined in dilute deuterochloroform solutions at 60 Mc./sec. The observed chemical shifts of the ring protons 3 and 5 of 4,6-disubstituted o-cresols are in good agreement with the values calculated from the shielding parameters of substituents by assuming the additivity rule. The spin-spin coupling constant between two ring protons is proportional to the sum of the electronegativities of the substituents 4 and 6. There are weak long-range couplings between the methyl and ring protons. It has been suggested that hyperconjugation contributes to thesee couplings." @default.
- W2007481875 created "2016-06-24" @default.
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- W2007481875 date "1965-08-01" @default.
- W2007481875 modified "2023-09-24" @default.
- W2007481875 title "The Nuclear Magnetic Resonance Spectra of Some 4,6-Disubstituted<i>o</i>-Cresols" @default.
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- W2007481875 doi "https://doi.org/10.1246/bcsj.38.1271" @default.
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