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- W2007486306 abstract "Diruthenium complex [Cp*Ru(μ-SPri)3RuCp*] (Cp* = η5-C5Me5) reacted with PhCH2Br to give [Cp*RuBr(μ-SPri)2RuCp*(SPri)] (3) and PhCH2CH2Ph. Treatment of 3 with HC≡CR (R = But, 4-MeC6H4) or H2 resulted in the formation of [Cp*RuBr(μ-SPri)2RuCp*(C≡CR)] (4) or [Cp*RuBr(μ-SPri)2RuCp*H] (5), respectively. Complex 5 was further converted into [Cp*RuR(μ-SPri)2RuCp*H] (6a: R = PhCH2; 6b: R = PhCH2CH2) by the reaction with RMgX (X = Cl, Br). In contrast to the inertness of 6b, 6a dissolved in benzene underwent dinuclear reductive elimination to give PhMe in high yield at room temperature, accompanied by the generation of [Cp*Ru(μ-SPri)2RuCp*]." @default.
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- W2007486306 date "1994-02-01" @default.
- W2007486306 modified "2023-09-25" @default.
- W2007486306 title "Stepwise Syntheses of a Series of Thiolate-Bridged Diruthenium Complexes [Cp<sup>*</sup>RuBr(μ-SPr<sup>i</sup>)<sub>2</sub>RuCp<sup>*</sup>X] (Cp<sup>*</sup>= η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>; X = SPr<sup>i</sup>, alkynyl, H) and [Cp<sup>*</sup>RuR(μ-SPr<sup>i</sup>)<sub>2</sub>RuCp<sup>*</sup>H] (R = CH<sub>2</sub>Ph, CH<sub>2</sub>CH<sub>2</sub>Ph). Facile Dinuclear Reductive Elimination of PhCH<sub>3</sub>from [Cp<sup>*</sup>Ru(CH<sub>2</sub>Ph)(μ-SPr<sup>i</sup>)<sub>2</sub>RuCp<…" @default.
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- W2007486306 doi "https://doi.org/10.1246/cl.1994.371" @default.
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