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- W2007488144 abstract "Heat treatment effect on red photoluminescence efficiency in p-GaP; Zn,O crystals is investigated and a strong NA (Zn acceptor concentration) dependence of formation rate of Zn-O complex is revealed. The results are quantitatively interpreted in terms of a reaction mechanism in which a substitutional zinc atom on the Ga site jumps into an interstitial site, diffuses in lattice, and is captured in a Ga vacancy neighboring the oxygen atom on the P site. Zn-O complex concentration is expressed by an exponential function of annealing time. Variation rate of the complex concentration is proportional to NA2 at low temperatures where dissociation constant K of Zn-O complex is smaller than NA, while it is proportional to NA at high temperatures where K is larger than NA. Dissociation constant and dissociation rate constant of Zn-O complex were determined as functions of temperature. 0.74 eV was obtained for dissociation activation energy." @default.
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- W2007488144 date "1972-06-01" @default.
- W2007488144 modified "2023-09-26" @default.
- W2007488144 title "Kinetics of Zn-O Complex Formation in GaP Crystal" @default.
- W2007488144 doi "https://doi.org/10.1143/jjap.11.860" @default.
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