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- W2007492049 abstract "Reaction of HBF4·OEt2 with IrH2(MeCN)P3+ (1) (P = PMe2Ph) in the presence of MeCN gives rapid conversion to cis, mer-IrH(MeCN)2P32+ and H2. The corresponding reaction with cis,mer-IrMe2(MeCN)P3+ is much slower, but gives the corresponding product, cis,mer-IrMe(MeCN)2P32+. In the absence of added MeCN, HBF4·OEt2 transforms the dihydride cation 1 to equimolar cis,mer-IrH(MeCN)2P32+ and IrH4P3+; 0.5 mol of acid suffices to effect this reaction. In the absence of added MeCN, the protonation of the dimethyl cation leads to the ether complex mer-IrMe(Et2O)(MeCN) P32+, which is subsequently scavenged by adventitious water to yield mer-IrMe(H2O)MeCN)P32+. The crystal structure of this aquo complex, as its BF4 salt, shows a chain of BF4− /IrMe(H2O)(MeCN)P32+ units held together by two hydrogen bonds to each water molecule. Crystallographic data for [IrMe(H2O)(NCMe)(PMe2Ph)3](BF4)2 (at − 169°C): a = 10.709(3) Å, b = 15.645(4), c = 10.481(2), β = 106.49(1)° with Z = 2 in space group P1." @default.
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- W2007492049 date "1992-02-01" @default.
- W2007492049 modified "2023-09-23" @default.
- W2007492049 title "Protonation of cationic hydride and alkyl complexes of Ir(III)" @default.
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- W2007492049 doi "https://doi.org/10.1016/0022-328x(92)80011-l" @default.
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