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- W2007493665 abstract "The problem of the reactivity of compounds containing hydroxyl, which are used in urethane formation, has been extensively discussed in the literature [1, 2]. This problem is particularly important when examining the kinetics of three-dimensional polymerization during the synthesis of crosslinked polyurethanes [3]. Many effects are difficult to explain except by employing concepts of varying reactivities of compounds containing hydroxyl in the system (polyester diol, triol, diol) and concerning a whole number of processes accompanying the formation of a three-dimensional structure of polyester urethane. This paper deals with the kinetics of the model reaction of m-chlorophenyl isocyanate (CPI) with polyester diol, trimethylol propane and 1,4-butanediol and explains their reactivities when mixed with each other. The possibility is examined of balancing the varying reactivities of materials containing hydroxyl by a catalyst, of which the mechanism of action is well known." @default.
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- W2007493665 date "1972-01-01" @default.
- W2007493665 modified "2023-10-17" @default.
- W2007493665 title "Kinetics of interaction of m-chlorophenyl isocyanate with glycols" @default.
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- W2007493665 doi "https://doi.org/10.1016/0032-3950(72)90130-x" @default.
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