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- W2007495653 abstract "The kinetics of partial oxidation of methanol to produce hydrogen was studied over a Cu(35.7 wt.-%)-ZnO catalyst in a continuous-flow reactor. A reaction mechanism was presented. A kinetic model was proposed which assumed the dissociative adsorption of methanol as the rate-determining step. Methoxide was assumed as the most abundant surface intermediate. The rate equation thus derived using the Langmuir-Hinshelwood-Hougen-Watson formulation satisfied the experimental results very well. It was found that the partial oxidation rate was second order in methanol concentration and had a pronounced maximum with respect to oxygen concentration." @default.
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- W2007495653 title "Kinetics of partial oxidation of methanol over a copper—zinc catalyst" @default.
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- W2007495653 doi "https://doi.org/10.1016/s0166-9834(00)80424-8" @default.
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