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- W2007514884 abstract "Abstract A novel chelate exchange reaction, leading to the formation of a series of N-alkyl substituent dependent mixed ligand isomeric complexes of the type Ni(R–AB)(AC') and Ni(R–AC)(AB') (Figure 1) are discussed. Here, AB and AC denote two different N-bonded isonitroso-β-keto-imino ligand moieties, while AB' and AC' are the corresponding O-bonded ligand moieties and R is an N-alkyl substituent. The isomeric complexes are suggested to be monomeric, neutral and diamagnetic with an asymmetric square planar geometry. The bonding isomerism of the isonitroso group in these complexes is discussed on the basis of the infrared and proton magnetic resonance spectral studies. A probable mechanism for the preparative route is also proposed." @default.
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- W2007514884 date "1978-09-01" @default.
- W2007514884 modified "2023-10-14" @default.
- W2007514884 title "BONDING ISOMERISM IN THE CHELATE-EXCHANGE REACTIONS OF ISONITROSO-β-KETO-IMINO ISOMERIC NICKEL(II) MIXED LIGAND COMPLEXES" @default.
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- W2007514884 doi "https://doi.org/10.1080/00958977808073086" @default.
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