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- W2007529123 abstract "Monolayers of propylene oxide were prepared on graphite monolayers on Pt(111) surfaces at 90 K and their reactions with gaseous H(D) atoms investigated using TDS and HREELS. I-propanol, n-propanol, acetone, water, propane, and propene were observed as reaction products. This rich chemistry is possible since H addition to propylene oxide leads to two radical intermediates via splitting of the C–O–C ring on either side of the oxygen. H addition to these radicals results in overall alcoholysis of propylene oxide. N-propanol is favored as a product over i-propanol due to the higher stability of the intermediate. Alternatively, via split-off of water, propene is formed from the radicals. These primary products undergo further reactions with H atoms: propene is hydrogenated towards propane, i-propanol reacts via a sequence of two H-abstractions to acetone. The reaction cross-section of H addition to propylene oxide of only 0.03 Å2 indicates that the ring splitting is compatible with a direct, Eley–Rideal type reaction." @default.
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- W2007529123 date "1999-02-01" @default.
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- W2007529123 title "Reactions of gaseous H atoms with propylene oxide monolayers adsorbed on graphite covered Pt(111) surfaces" @default.
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- W2007529123 doi "https://doi.org/10.1016/s0039-6028(98)00812-7" @default.
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