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• W2007551650 abstract "Abstract The half‐sandwich rare‐earth complexes [M III (acac)(TClPP)] (M=Sm, Eu, Y; TClPP= meso ‐tetrakis(4‐chlorophenyl)porphyrinate; acac=acetylacetonate), generated in situ from [M(acac) 3 ]⋅ n H 2 O and H 2 (TClPP), were treated with 1,8,15,22‐tetrakis(3‐pentyloxy)phthalocyanine [H 2 {Pc(α‐OC 5 H 11 ) 4 }] (Pc=phthalocyaninate) under reflux in n ‐octanol to yield both the neutral nonprotonated and protonated (phthalocyaninato)(porphyrinato) rare‐earth double‐decker complexes, [M III {Pc(α‐OC 5 H 11 ) 4 }(TClPP)] ( 1–3 ) and [M III H{Pc(α‐OC 5 H 11 ) 4 }(TClPP)] ( 4–6 ), respectively. In contrast, reaction of [Y III (acac)(TClPP)] with 1,4,8,11,15,18,22,25‐octakis(1‐butyloxy)phthalocyanine [H 2 Pc(α‐OC 4 H 9 ) 8 ] gave only the protonated double‐decker complex [Y III H{Pc(α‐OC 4 H 9 ) 8 }(TClPP)] ( 7 ). These observations clearly show the importance of the number and positions of substituents on the phthalocyanine ligand in controlling the nature of the (phthalocyaninato)(porphyrinato) rare‐earth double‐deckers obtained. In particular, α‐alkoxylation of the phthalocyanine ligand is found to stabilize the protonated form, a fact supported by molecular‐orbital calculations. A combination of mass spectrometry, NMR, UV‐visible, near‐IR, MCD, and IR spectroscopy, and X‐ray diffraction analyses, facilitated the differentiation of the newly prepared neutral nonprotonated and protonated double‐decker complexes. The crystal structure of the protonated form has been determined for the first time." @default.
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• W2007551650 date "2006-01-23" @default.
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• W2007551650 title "Controlling the Nature of Mixed (Phthalocyaninato)(porphyrinato) Rare-Earth(III) Double-Decker Complexes: The Effects of Nonperipheral Alkoxy Substitution of the Phthalocyanine Ligand" @default.
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• W2007551650 doi "https://doi.org/10.1002/chem.200500733" @default.
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