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• W2007558419 endingPage "3608" @default.
• W2007558419 startingPage "3603" @default.
• W2007558419 abstract "The syntheses and structures of a [2×1+1×2] cocrystal [{CuIIL1NaI(H2O)2}{CuIIL1}2](NO3) (1) and [3×1+5×1] cocrystal [{(CuIIL1)2KI}(NO3)]·[{(CuIIL1)3KI2(μ-NO3)}(NO3)]·0.2H2O (2) derived from the hexadentate Schiff base compartmental ligand N,N′-ethylenebis(3-ethoxysalicylaldimine) (H2L1) are described. Compounds 1 and 2 crystallize in triclinic P1̅ and monoclinic P21/c systems, respectively. The structure of 1 consists of the [CuIIL1ΝaI(H2O)3]+ cation and two mononuclear [CuIIL1] moieties. In the dinuclear [CuIIL1ΝaI(H2O)3]+ cation, the metal centers are doubly bridged by the two phenolate oxygen atoms. Each of the two coordinated water molecules of the dinuclear unit is encapsulated in the O4 cavities of the two mononuclear [CuIIL1] moieties resulting in the formation of a [2×1+1×2] cocrystal. In compound 2, one trinuclear double-decker system [{(CuIIL1)2KI}(NO3)] and one pentanuclear triple-decker system [{(CuIIL1)3KI2(μ-NO3)}(NO3)] are cocrystallized. Evidently, compound 2 is a [3×1+5×1] cocrystal. Structural resemblance of 3d metal ions with Na(I) and a rare example of double-decker−triple-decker cocrystal are the major outcomes of the present investigation." @default.
• W2007558419 created "2016-06-24" @default.
• W2007558419 creator A5004624405 @default.
• W2007558419 creator A5024366756 @default.
• W2007558419 creator A5064096309 @default.
• W2007558419 creator A5072231735 @default.
• W2007558419 creator A5073991542 @default.
• W2007558419 creator A5076499503 @default.
• W2007558419 date "2009-07-06" @default.
• W2007558419 modified "2023-10-01" @default.
• W2007558419 title "Cocrystallized Dinuclear−Mononuclear Cu^II₃Na^I and Double-Decker−Triple-Decker Cu^II₅K^I₃ Complexes Derived from <i>N</i>,<i>N</i>′-Ethylenebis(3-ethoxysalicylaldimine)" @default.
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• W2007558419 doi "https://doi.org/10.1021/cg900341r" @default.

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