Matches in SemOpenAlex for { <https://semopenalex.org/work/W2007567468> ?p ?o ?g. }
- W2007567468 endingPage "3978" @default.
- W2007567468 startingPage "3978" @default.
- W2007567468 abstract "The organic palladium complex Pd(H2bpydc)Cl2 (H2bpydc = 2,2′-bipyridine-5,5′-dicarboxylic acid) was immobilized on a porous metal–organic framework UiO-67 (Zr6O4(OH)4(bpdc)6, bpdc = para-biphenyldicarboxylate) using a direct incorporation strategy. The use of a large amount of the H2bpdc ligand (90 mol% of the mixed ligands) that can't chelate the Pd complex allowed the formation of isolated Pd single active sites uniformly distributed in the MOF network. Pd(II) doped UiO-67 is isostructural to the parent UiO-67 framework, with a high surface area and pore volume of ca. 2000 m2 g−1 and 0.79 cm3 g−1, respectively. The material was highly efficient in the catalytic conversion of aryl chlorides, showing remarkably higher activity than the homogeneous Pd counterparts. High yields were achieved in Heck and Suzuki–Miyaura coupling reactions of chloroarenes bearing a wide range of substituents. Moreover, the catalyst was recoverable and reusable, giving essentially identical activity after at least 5 cycles. The combination of the advantages of both homogeneous molecular Pd catalysts and solid MOF structures in this system may bring new opportunity in the development of highly active heterogeneous palladium catalysts for a variety of Pd-catalyzed transformations." @default.
- W2007567468 created "2016-06-24" @default.
- W2007567468 creator A5021523686 @default.
- W2007567468 creator A5034933969 @default.
- W2007567468 creator A5048067979 @default.
- W2007567468 creator A5058150746 @default.
- W2007567468 creator A5067244844 @default.
- W2007567468 date "2014-07-03" @default.
- W2007567468 modified "2023-10-01" @default.
- W2007567468 title "A molecular Pd(<scp>ii</scp>) complex incorporated into a MOF as a highly active single-site heterogeneous catalyst for C–Cl bond activation" @default.
- W2007567468 cites W1970880665 @default.
- W2007567468 cites W1976233554 @default.
- W2007567468 cites W1977173659 @default.
- W2007567468 cites W1979681627 @default.
- W2007567468 cites W1986238480 @default.
- W2007567468 cites W1994612835 @default.
- W2007567468 cites W1997410309 @default.
- W2007567468 cites W1999703617 @default.
- W2007567468 cites W2002855161 @default.
- W2007567468 cites W2006792934 @default.
- W2007567468 cites W2020353271 @default.
- W2007567468 cites W2022463278 @default.
- W2007567468 cites W2025256050 @default.
- W2007567468 cites W2029164545 @default.
- W2007567468 cites W2046415634 @default.
- W2007567468 cites W2046552846 @default.
- W2007567468 cites W2064311631 @default.
- W2007567468 cites W2068339282 @default.
- W2007567468 cites W2075535386 @default.
- W2007567468 cites W2094145140 @default.
- W2007567468 cites W2116601927 @default.
- W2007567468 cites W2121454445 @default.
- W2007567468 cites W2135193488 @default.
- W2007567468 cites W2135871575 @default.
- W2007567468 cites W2136833044 @default.
- W2007567468 cites W2155579681 @default.
- W2007567468 cites W2157871632 @default.
- W2007567468 cites W2163488899 @default.
- W2007567468 cites W2164401501 @default.
- W2007567468 cites W2312866138 @default.
- W2007567468 cites W2321905829 @default.
- W2007567468 cites W4248401078 @default.
- W2007567468 cites W2951851261 @default.
- W2007567468 doi "https://doi.org/10.1039/c4gc00314d" @default.
- W2007567468 hasPublicationYear "2014" @default.
- W2007567468 type Work @default.
- W2007567468 sameAs 2007567468 @default.
- W2007567468 citedByCount "123" @default.
- W2007567468 countsByYear W20075674682014 @default.
- W2007567468 countsByYear W20075674682015 @default.
- W2007567468 countsByYear W20075674682016 @default.
- W2007567468 countsByYear W20075674682017 @default.
- W2007567468 countsByYear W20075674682018 @default.
- W2007567468 countsByYear W20075674682019 @default.
- W2007567468 countsByYear W20075674682020 @default.
- W2007567468 countsByYear W20075674682021 @default.
- W2007567468 countsByYear W20075674682022 @default.
- W2007567468 countsByYear W20075674682023 @default.
- W2007567468 crossrefType "journal-article" @default.
- W2007567468 hasAuthorship W2007567468A5021523686 @default.
- W2007567468 hasAuthorship W2007567468A5034933969 @default.
- W2007567468 hasAuthorship W2007567468A5048067979 @default.
- W2007567468 hasAuthorship W2007567468A5058150746 @default.
- W2007567468 hasAuthorship W2007567468A5067244844 @default.
- W2007567468 hasConcept C109474758 @default.
- W2007567468 hasConcept C115624301 @default.
- W2007567468 hasConcept C116569031 @default.
- W2007567468 hasConcept C150394285 @default.
- W2007567468 hasConcept C161790260 @default.
- W2007567468 hasConcept C168896768 @default.
- W2007567468 hasConcept C170493617 @default.
- W2007567468 hasConcept C175583648 @default.
- W2007567468 hasConcept C178790620 @default.
- W2007567468 hasConcept C179104552 @default.
- W2007567468 hasConcept C179366358 @default.
- W2007567468 hasConcept C185592680 @default.
- W2007567468 hasConcept C188027245 @default.
- W2007567468 hasConcept C197404232 @default.
- W2007567468 hasConcept C205188671 @default.
- W2007567468 hasConcept C21951064 @default.
- W2007567468 hasConcept C2780263894 @default.
- W2007567468 hasConcept C2781076698 @default.
- W2007567468 hasConcept C502130503 @default.
- W2007567468 hasConcept C55493867 @default.
- W2007567468 hasConceptScore W2007567468C109474758 @default.
- W2007567468 hasConceptScore W2007567468C115624301 @default.
- W2007567468 hasConceptScore W2007567468C116569031 @default.
- W2007567468 hasConceptScore W2007567468C150394285 @default.
- W2007567468 hasConceptScore W2007567468C161790260 @default.
- W2007567468 hasConceptScore W2007567468C168896768 @default.
- W2007567468 hasConceptScore W2007567468C170493617 @default.
- W2007567468 hasConceptScore W2007567468C175583648 @default.
- W2007567468 hasConceptScore W2007567468C178790620 @default.
- W2007567468 hasConceptScore W2007567468C179104552 @default.
- W2007567468 hasConceptScore W2007567468C179366358 @default.
- W2007567468 hasConceptScore W2007567468C185592680 @default.
- W2007567468 hasConceptScore W2007567468C188027245 @default.
- W2007567468 hasConceptScore W2007567468C197404232 @default.