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- W2007596803 abstract "Fluorination of poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) leads to narrowing of its window of electrochemical stability in a cathodic range of potentials. It is found this is connected with appearance of both perfluorinated and incompletely fluorinated units in the polymer. The former units are liable to electrochemical reduction (at potentials <−2.0 V) followed by elimination of fluorine anions and the latter react with basic products (generated at potentials <−1.8 V) of electrochemical reduction of the background solution. In the both cases this results in appearance of conjugated multiple bonds in the fluorinated macromolecules. Quantities of these units in fluorinated PPO were determined with a help of direct and indirect electrochemical reductive degradation techniques." @default.
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- W2007596803 date "2000-01-01" @default.
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- W2007596803 title "Electrochemical stability and transformations of fluorinated poly(2,6-dimethyl-1,4-phenylene oxide)" @default.
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- W2007596803 doi "https://doi.org/10.1016/s0141-3910(00)00135-x" @default.
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