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- W2007606889 abstract "The organic-inorganic hybrid, PSS-silica composite material was developed for the immobilization of tris(2,2′-bipyridyl)ruthenium(II) on glassy carbon electrode via ion-exchange (PSS stands for poly(sodium 4-styrene-sulfonate)). The electrochemiluminescence (ECL) and electrochemistry of immobilized in the composite thin films have been investigated with tripropylamine (TPA) as the coreactant. The immobilized underwent a surface process. The modified electrode was used for the ECL detection of TPA and showed high sensitivity. Detection limit was 0.1 μmol L−1 for TPA (S/N=3) with a linear range from 0.5 μmol L−1 to 5 mmol L−1 (R=0.998). Moreover, the resulting modified electrode was stable over six months and the good stability may be due to the strong interaction between and the high ion-exchangeable PSS-silica composite films on GCE. Compared with other materials, the PSS-silica composite films containing incorporated showed improved sensitivity and long-term stability. Thus, such composite thin film can be a promising material for the construction of ECL sensor." @default.
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- W2007606889 date "2002-06-01" @default.
- W2007606889 modified "2023-09-25" @default.
- W2007606889 title "Electrochemiluminescence of Tris(2,2′-bipyridyl)ruthenium(II) Ion-Exchanged in Polyelectrolyte-Silica Composite Thin-Films" @default.
- W2007606889 doi "https://doi.org/10.1002/1521-4109(200206)14:12<853::aid-elan853>3.0.co;2-d" @default.
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