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- W2007609007 abstract "The polarized Raman spectra of ammonium dihydrogenphosphate (ADP) were observed at room temperature. The observed spectra are explained basically in terms of D2d symmetry, since the observed spectra differ substantially from those expected for lower symmetry, especially as regards Raman intensity. It is considered that the high symmetry is due to proton tunnellings, which give rise to the delocalization of protons. The normal modes and the Raman intensity of ADP were analysed satisfactorily on the basis of D2d symmetry, which also supports the delocalization of protons. The low-lying wing in the E species arises from relaxation modes due to translational motions which result from proton tunnellings. © 1998 John Wiley & Sons, Ltd." @default.
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- W2007609007 date "1998-02-01" @default.
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- W2007609007 title "Normal coordinate analysis and structure of ammonium dihydrogenphosphate" @default.
- W2007609007 doi "https://doi.org/10.1002/(sici)1097-4555(199802)29:2<153::aid-jrs206>3.0.co;2-t" @default.
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