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- W2007615479 abstract "The 1,3-Dipolar cycloaddition of 3,4,5,6-tetrahydropyridine 1-oxide (1) to 5-methyl-2(5H)-furanone (2) yields adducts 3, 4, and 5, whose stereochemistry has been established by a detailed study of their low-temperature 1H-NMR spectra. The major adduct, 4, arises from an exo transition state and an anti approach, indicating the dominance of steric factors over secondary orbital interactions. Stereochemische Analyse der Cycloaddition eines cyclischen Nitrons an 5-Methyl-2(5H)-furanon Die 1,3-dipolare Cycloaddition von 3,4,5,6-Tetrahydropyridin-1-oxid (1) an 5-Methyl-2(5H)furanon (2) liefert die Addukte 3, 4 und 5, deren Stereochemie durch sorgfältige Analyse der Tieftemperatur-1H-NMR-Spektren bestimmt wurde. Das Hauptprodukt, 4, Ergebnis eines exo-Übergangszustandes und einer anti-Annäherung, weist auf die Überlegenheit sterischer Faktoren über sekundäre Orbitalwechselwirkungen hin." @default.
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- W2007615479 date "1989-09-01" @default.
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- W2007615479 title "Stereochemical study on the cycloaddition of a cyclic nitrone to 5-methyl-2(5H)-furanone" @default.
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- W2007615479 doi "https://doi.org/10.1002/cber.19891220916" @default.
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