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- W2007622016 abstract "1,4-Di(isopropyl)-1,4-diazabutadiene as a Reagent for the Trapping of Monomeric Fragments of the Tetragalliumcluster Ga4[C(SiMe3)3]4 – Formation of an Unsaturated GaN2C2 Heterocycle and an Oxidation Product Containing a Ga-O-O-Ga Group The tetrahedral tetragallium cluster Ga4[C(SiMe3)3]4 (1) dissociates upon dissolution to yield the monomeric fragments Ga-R [R = C(SiMe3)3]. These monomers could be trapped now by the treatment of their solutions with 1,4-di(isopropyl)-1,4-diazabutadiene. The product of the cycloaddition reaction (2) possesses a five-membered GaN2C2 heterocycle with a coordinatively unsaturated gallium atom and an endocyclic C=C double bond. 2 is rather sensitive towards oxidation by traces of air. The contact with oxygen yielded a digallium peroxide [(C2N2iPr2)RGa-O-O-GaR(C2N2iPr2)] (3) which was isolated in a very low yield only and which has a gallium atom attached to each oxygen atom of the inner peroxo group. Both chelating ligands of 3 possess an unpaired electron." @default.
- W2007622016 created "2016-06-24" @default.
- W2007622016 creator A5032754495 @default.
- W2007622016 creator A5067012584 @default.
- W2007622016 creator A5070674608 @default.
- W2007622016 date "2005-06-01" @default.
- W2007622016 modified "2023-10-18" @default.
- W2007622016 title "1,4-Di(isopropyl)-1,4-diazabutadien als Abfangreagenz für monomere Bruchstücke des Tetragalliumclusters Ga4[C(SiMe3)3]4 - Bildung eines ungesättigten GaN2C2-Heterocyclus und eines Oxidationsprodukts mit Ga-O-O-Ga-Gruppe" @default.
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