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- W2007657878 abstract "A highly sensitive method for determination of rhodium by laser thermal lens spectrometry based on the colour reaction between rhodium and the new chromogenic reagent 5-bromo-(2-thiazolylazo)-5-diethylaminobenzoic acid (5-Br-TADEB) has been developed. The experimental results show that in a acetic acid-sodium acetate buffer solution of pH 4.0–5.7 and in the presence of acetone, rhodium reacts with 5-Br-TADEB to form a 1 : 2 stable blue complex exhibiting an absorption maximum at 632 nm which is well-matched to the wavelength of the laser beam used (λ = 632.8 nm). The detection limit and linear range of rhodium(III) are 0.004 μg mL−1 and 0.01–0.08 μg mL−1, respectively. The method has also been applied to determine rhodium in catalyst samples with satisfactory results." @default.
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- W2007657878 date "2001-08-31" @default.
- W2007657878 modified "2023-09-26" @default.
- W2007657878 title "LASER THERMAL LENS SPECTROMETRIC DETERMINATION OF RHODIUM BY THE NEW CHROMOGENIC REAGENT 5-BROMO-(2-THIAZOLYLAZO)-5-DIETHYLAMINOBENZOIC ACID" @default.
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- W2007657878 doi "https://doi.org/10.1081/al-100106847" @default.
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