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- W2007661843 abstract "1.|The ESR spectra of spin labelled fatty acids dissolved in dispersions of lecithin and lecithin-cholesterol mixtures show a marked pH dependence. The motion of the spin probes becomes more anisotropic as the pH is increased from 4 to 7. The increase in anisotropy is attributed to a change in location of the spin probes on ionisation of their carboxylic acid groups. 2.|It is proposed that the spin probes are anchored in the lecithin head-group regions by hydrogen-bonding to the phosphate group at low pH (below pH 4) and by ion-pairing with the choline group at high pH (above pH 7). The distance between these two locations, estimated from the change in the ESR order parameter is about 6 Å, suggesting that the choline head-group is extended perpendicular to the plane of the bilayer." @default.
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- W2007661843 date "1974-08-01" @default.
- W2007661843 modified "2023-10-14" @default.
- W2007661843 title "The pH-dependence of ESR spectra from nitroxide probes in lecithin dispersions" @default.
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- W2007661843 doi "https://doi.org/10.1016/0005-2736(74)90011-x" @default.
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