FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2007668512> ?p ?o ?g. }

• W2007668512 endingPage "114" @default.
• W2007668512 startingPage "106" @default.
• W2007668512 abstract "Many physical phenomena are affected by the structure of water interfaces, yet it remains an active and controversial subject. A great deal of recent theoretical endeavour and computer simulations question the validity of the Onsager Samaras theory of the ion-free interface between an electrolyte solution and an hydrophobic surface. Experimental results play a crucial role in assessing the legitimacy of the theories. Experimental data are scarce, while simulation results suggest an increasing surface affinity of ions with increasing chaotropic character, in dramatic contradiction to the classical view. Chromatography is a powerful separative technique, but we originally used it as a tool to detect the adsorption of chloride electrolytes and sodium electrolytes, strongly expected to shun any dielectric boundary, onto an hydrophobic surface, and to rank ions according to their adsorbophilicities. Frontal analysis gave unequivocal experimental evidence to this unexpected phenomenon and it was used to quantify it. The infinite dilution equilibrium constants for adsorption of kosmotropes and chaotropes onto the interface were obtained and contrasted to the Jones–Dole B viscosity coefficients, that is a common quantifier of the Hofmeister effect. It is clear that (i) the more chaotropic the ion is, the more it contributes to the global adsorbophilicity of the electrolyte; (ii) the influence of the variable anion is more than twofold that of the variable cation, thereby confirming a robust observation in many other physical systems. Standard free energy of adsorption for each electrolyte was calculated and its reliability was commented upon. The central issue in this paper is the effective and ascertained adsorption of electrolytes onto an hydrophobic surface and the fact that the adsorbophilicity of an electrolyte may be inferred from its position in the Hofmeister series." @default.
• W2007668512 created "2016-06-24" @default.
• W2007668512 creator A5008149011 @default.
• W2007668512 creator A5073223623 @default.
• W2007668512 date "2013-11-01" @default.
• W2007668512 modified "2023-09-27" @default.
• W2007668512 title "Chromatography and the hundred year mystery of inorganic ions at aqueous interfaces: Adsorption of inorganic ions at the Porous Graphitic Carbon Aqueous Interface follows the Hofmeister series" @default.
• W2007668512 cites W1571744663 @default.
• W2007668512 cites W1605936672 @default.
• W2007668512 cites W1966165119 @default.
• W2007668512 cites W196865893 @default.
• W2007668512 cites W1972175237 @default.
• W2007668512 cites W1973664279 @default.
• W2007668512 cites W1974021330 @default.
• W2007668512 cites W1975727760 @default.
• W2007668512 cites W1978213309 @default.
• W2007668512 cites W1979851970 @default.
• W2007668512 cites W1981115950 @default.
• W2007668512 cites W1981651552 @default.
• W2007668512 cites W1991263911 @default.
• W2007668512 cites W1996009737 @default.
• W2007668512 cites W2001861985 @default.
• W2007668512 cites W2003494090 @default.
• W2007668512 cites W2004200788 @default.
• W2007668512 cites W2012541641 @default.
• W2007668512 cites W2020087991 @default.
• W2007668512 cites W2021413265 @default.
• W2007668512 cites W2021580709 @default.
• W2007668512 cites W2024568712 @default.
• W2007668512 cites W2030163787 @default.
• W2007668512 cites W2034037530 @default.
• W2007668512 cites W2039845426 @default.
• W2007668512 cites W2045193605 @default.
• W2007668512 cites W2045713117 @default.
• W2007668512 cites W2050066823 @default.
• W2007668512 cites W2053614018 @default.
• W2007668512 cites W2054342626 @default.
• W2007668512 cites W2057426668 @default.
• W2007668512 cites W2059737929 @default.
• W2007668512 cites W2061350765 @default.
• W2007668512 cites W2063708874 @default.
• W2007668512 cites W2066811718 @default.
• W2007668512 cites W2069370854 @default.
• W2007668512 cites W2073870395 @default.
• W2007668512 cites W2074005803 @default.
• W2007668512 cites W2075320109 @default.
• W2007668512 cites W2080343882 @default.
• W2007668512 cites W2081503651 @default.
• W2007668512 cites W2082853624 @default.
• W2007668512 cites W2082964184 @default.
• W2007668512 cites W2085509123 @default.
• W2007668512 cites W2086875015 @default.
• W2007668512 cites W2088960562 @default.
• W2007668512 cites W2089190681 @default.
• W2007668512 cites W2091842006 @default.
• W2007668512 cites W2095100718 @default.
• W2007668512 cites W2095446120 @default.
• W2007668512 cites W2095499638 @default.
• W2007668512 cites W2095919326 @default.
• W2007668512 cites W2108285714 @default.
• W2007668512 cites W2109898265 @default.
• W2007668512 cites W2128710909 @default.
• W2007668512 cites W2135240384 @default.
• W2007668512 cites W2325087798 @default.
• W2007668512 cites W2326055143 @default.
• W2007668512 cites W2329780841 @default.
• W2007668512 cites W2439649890 @default.
• W2007668512 cites W2585502767 @default.
• W2007668512 cites W2620966688 @default.
• W2007668512 cites W2978641146 @default.
• W2007668512 cites W3100428571 @default.
• W2007668512 cites W3105436407 @default.
• W2007668512 cites W2027034603 @default.
• W2007668512 doi "https://doi.org/10.1016/j.chroma.2013.09.013" @default.
• W2007668512 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24075459" @default.
• W2007668512 hasPublicationYear "2013" @default.
• W2007668512 type Work @default.
• W2007668512 sameAs 2007668512 @default.
• W2007668512 citedByCount "3" @default.
• W2007668512 countsByYear W20076685122013 @default.
• W2007668512 countsByYear W20076685122014 @default.
• W2007668512 crossrefType "journal-article" @default.
• W2007668512 hasAuthorship W2007668512A5008149011 @default.
• W2007668512 hasAuthorship W2007668512A5073223623 @default.
• W2007668512 hasConcept C102362939 @default.
• W2007668512 hasConcept C121332964 @default.
• W2007668512 hasConcept C145148216 @default.
• W2007668512 hasConcept C147789679 @default.
• W2007668512 hasConcept C150394285 @default.
• W2007668512 hasConcept C159467904 @default.
• W2007668512 hasConcept C17525397 @default.
• W2007668512 hasConcept C178790620 @default.
• W2007668512 hasConcept C184651966 @default.
• W2007668512 hasConcept C185592680 @default.
• W2007668512 hasConcept C43617362 @default.
• W2007668512 hasConcept C58436429 @default.
• W2007668512 hasConcept C68801617 @default.
• W2007668512 hasConcept C97355855 @default.

• next