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- W2007668814 abstract "Phase relations in the system NiAl2O4Ni2SiO4 were studied in the pressure range 1.5 ∼ 13.0 GPa and in the temperature range 800 ∼ 1450°C. Two new phases, IV and V, were found in regions of pressure higher than 4 GPa. Phase V disproportionates into a mixture of Ni2SiO4-spinel, NiO, and Al2O3 at approximately 9.5 GPa and 1100°C. Phases III, IV, and V form a solid solution in some compositional range: phases IV and V have a composition around NiAl2O4·Ni2SiO4, whereas phase III spreads from NiAl2O4·Ni2SiO4 to the NiAl2O4-rich side. All the phases I ∼ V are structurally considered to be spinel derivatives, “spinelloids,” with three kinds of tetrahedral groups; isolated tetrahedra TO4, linked ones T2O7, and triply linked ones T3O10. The ratios of isolated tetrahedra to linked ones are large in the higher-pressure phases and small in the lower-pressure phases. The difference of compositional range of phase III from that of phases IV and V is possibly explained by the avoidance of linked tetrahedra such as O3AlOAlO3." @default.
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- W2007668814 date "1982-09-01" @default.
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- W2007668814 title "The system NiAl2O4Ni2SiO4 at high pressures and temperatures: Spinelloids with spinel-related structures" @default.
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- W2007668814 doi "https://doi.org/10.1016/0022-4596(82)90372-3" @default.
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