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- W2007671159 abstract "The synthesis of benzocyclobutene by the photochemical desulfonylation of 1,3-dihydroisothianaphthene-2, 2-dioxide has been studied and the following results obtained; 1) The irradiation considerably accelerates the desulfonylation of the sulfone, while the ultravioletlight has no remarkable effect on the molar ratio of the formed benzocyclobutene and 1,2,5,6-dibenzocycloöctadiene. 2) The rate of desulfonylation is independent of pressure, and the reaction pressure plays a very important role in the further reaction of the intermediate o-xylylene biradical produced by the desulfonylation." @default.
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- W2007671159 date "1964-10-01" @default.
- W2007671159 modified "2023-10-17" @default.
- W2007671159 title "Synthesis of Benzocyclobutene by Photochemical Desulfonylation" @default.
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- W2007671159 doi "https://doi.org/10.1246/bcsj.37.1410" @default.
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