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• W2007677030 abstract "Adsorption and reactions of 2-methylpropene (isobutene) on mordenite were investigated between 150 and 300 K by infrared (IR) spectroscopy. The methyl groups of isobutene interacted with the acidic OH groups of mordenite below 160 K, which was converted to the strongly interacted π-bonded isobutene to the acidic OH groups (π-complex). Above 200 K, the π-bonded isobutene dimerized even under evacuation condition. The stable 2,4,4-trimethyl-2-pentoxy species was identified by FT-IR by comparison with the spectra of the adsorbed C8 olefins. The expected monomeric reaction intermediate, the 2-methyl-2-propoxy (tert-butoxy) species, was not observed. This is probably due to the rapid migration and reaction of the adsorbed isobutene molecules." @default.
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• W2007677030 date "1999-06-17" @default.
• W2007677030 modified "2023-10-11" @default.
• W2007677030 title "Stable Dimerized Alkoxy Species of 2-Methylpropene on Mordenite Zeolite Studied by FT-IR" @default.
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• W2007677030 doi "https://doi.org/10.1021/jp990444l" @default.
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