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- W2007682006 abstract "Thermogravimetric (TG) curves are presented for heating Ba2YCu3O7 up to 1000°C in CO2, CO, several mixtures of CO2 in O2, and in wet O2 and wet CO2. In pure CO2 there is a small weight loss up to about 400°C, presumably due to O2 evolution caused by the low PO2. This decrease in weight is followed by a large weight gain up to about 950°C at which point the carbonate formed just begins to decompose. The behavior in CO is similar except the loss of O2 is much greater. In wet O2 there is a very slight weight gain beginning around 300°C followed by the normal loss of weight associated with O2 evolution decomposition of any hydroxide formed earlier. Sintered toroids and bars of Ba2YCu3O7 were given isothermal treatments in pure CO2, 1% CO2 in O2, and wet O2 at selected temperatures. Treatments in CO2 for 1000 minutes at 100°C intervals led to a progressive decrease in conductivity and Jc until at 500°C the material was completely semiconducting. Behavior in 1% CO2 in O2 was similar. In wet O2 the conductivity and Jc went through a minimum at about 200°C. Samples degraded by CO2 or H2O could be nearly regenerated by firing above 900°C in O2 and either annealed or slow cooled in O2." @default.
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- W2007682006 date "1988-10-01" @default.
- W2007682006 modified "2023-10-14" @default.
- W2007682006 title "Some effects of CO2, CO and H2O upon the properties of Ba2YCu3O7" @default.
- W2007682006 cites W1994271767 @default.
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- W2007682006 doi "https://doi.org/10.1016/0025-5408(88)90275-9" @default.
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