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- W2007688511 abstract "The conformation of 5′-adenosine monophosphate (AMP) in D2O and in [2H6]DMSO was studied using nuclear Overhauser effects together with lanthanide-induced relaxation effects and vicinal coupling constants. The conformation of 5′-AMP through the glycosidic bond was studied in detail using a simple two-state model and continuous distributions derived from potential-energy calculations. Either of the two models clearly indicates a base conformation for 5′-AMP in D2O within the anti-region and a flexible syn–anti equilibrium in [2H6]DMSO. These different flexibilities in the two solvents illustrate the importance of solute–solvent interactions in the definition of the conformation of a flexible solute in solution." @default.
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- W2007688511 date "1983-01-01" @default.
- W2007688511 modified "2023-10-16" @default.
- W2007688511 title "Solvent effects on the conformation of nucleotides. Part 1. The conformation of 5′-adenosine monophosphate in water–dimethyl sulphoxide using nuclear Overhauser effects and lanthanide relaxation probes" @default.
- W2007688511 doi "https://doi.org/10.1039/p29830001693" @default.
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