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- W200770147 abstract "A variety of silyl- and alkyl-germylene precursors have been synthesized and subsequently pyrolyzed in the gas phase. Arrhenius parameters were obtained employing a pulsed-stirred flow reactor for these unimolecular decompositions. These precursors are divided into two major categories by mechanism of germylene extrusion: α-elimination precursors and germylacetylenes. The extrusion of germylenes from germylacetylene precursors is of primary interest. A mechanism is proposed employing a germacyclopropene intermediate. Evidence supporting this mechanism is presented. In the process of exploring germylacetylenes as germylene precursors, an apparent dyatropic rearrangement between germanium and silicon was observed. This rearrangement was subsequently explored." @default.
- W200770147 created "2016-06-24" @default.
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- W200770147 date "1993-12-07" @default.
- W200770147 modified "2023-10-16" @default.
- W200770147 title "Gas phase thermochemistry of organogermanium compounds" @default.
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- W200770147 doi "https://doi.org/10.2172/10112831" @default.
- W200770147 hasPublicationYear "1993" @default.
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