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- W2007702845 abstract "Cobalt catalysts supported on unsilylated and silylated SBA-15 were prepared by incipient wetness impregnation and characterized by elemental analysis, N2 adsorption-desorption, X-ray diffraction, H2 temperature-programmed reduction, H2 temperature-programmed desorption, and oxygen titration. Their catalytic properties for Fischer-Tropsch synthesis were evaluated in a fixed-bed reactor. The results show that the interaction between cobalt and the support was decreased, and the reducibility of the cobalt oxide species was more facile on the silylated Co/SBA-15 catalyst. With increasing (CH3)3SiCl loading, the surface coverage of the trimethylsilyl group increased, and the cobalt cluster size was larger. The higher activity of the silylated 10%Co/SBA-15 catalysts was ascribed to its improved reducibility. The increase in selectivity for C5+ hydrocarbons was attributed to the increase in cobalt cluster size." @default.
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- W2007702845 date "2009-11-01" @default.
- W2007702845 modified "2023-09-25" @default.
- W2007702845 title "Effect of Silylation of SBA-15 on Its Supported Cobalt Catalysts for Fischer-Tropsch Synthesis" @default.
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- W2007702845 doi "https://doi.org/10.1016/s1872-2067(08)60141-2" @default.
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