Matches in SemOpenAlex for { <https://semopenalex.org/work/W2007704294> ?p ?o ?g. }
Showing items 1 to 100 of
100
with 100 items per page.
- W2007704294 endingPage "27" @default.
- W2007704294 startingPage "11" @default.
- W2007704294 abstract "Abstract Hydrogen and oxygen adsorption properties of ruthenium surfaces are characterized and shown to be analogous to those of other noble metals. Ruthenium dissolves on potential cycles, the rate of dissolution on cycles to 1.54 V being much greater than for Pd, Rh, Ir, Pt and Au. Treatment in hot chromic acid or potential cycling to 1.3 V or above results in significant changes in the voltammogram. X-ray emission spectroscopy has demonstrated that these changes are associated with the formation and growth of an oxygen-containing layer on the ruthenium surface. Electron micrographic analysis of the surface layer included in replicas revealed that the layer is essentially amorphous. Correlations between the thickness of the layer from replica shadowing experiments and X-ray emission measurements indicated that the composition of the layer at 0.03 V was predominantly RuO with a considerable degree of non-stoichiometry. The charge on the voltammogram when oxide is present is interpreted in terms of oxidation of hydrated RuO to hydrated RuO 2 by a mechanism involving the addition and removal of protons, with corresponding changes in the valence state of the metal atom. Comparisons are made with the properties of thermally-produced RuO 2 ." @default.
- W2007704294 created "2016-06-24" @default.
- W2007704294 creator A5012032003 @default.
- W2007704294 creator A5021161979 @default.
- W2007704294 creator A5061882933 @default.
- W2007704294 date "1978-05-01" @default.
- W2007704294 modified "2023-10-11" @default.
- W2007704294 title "A study of ruthenium electrodes by cyclic voltammetry and X-ray emission spectroscopy" @default.
- W2007704294 cites W1548335168 @default.
- W2007704294 cites W1596008697 @default.
- W2007704294 cites W1979807742 @default.
- W2007704294 cites W1985877259 @default.
- W2007704294 cites W1999888851 @default.
- W2007704294 cites W2018868940 @default.
- W2007704294 cites W2029698723 @default.
- W2007704294 cites W2031961184 @default.
- W2007704294 cites W2046853942 @default.
- W2007704294 cites W2059449499 @default.
- W2007704294 cites W2066748619 @default.
- W2007704294 cites W2068612441 @default.
- W2007704294 cites W2078058778 @default.
- W2007704294 cites W2078713153 @default.
- W2007704294 cites W2079138250 @default.
- W2007704294 cites W2079815617 @default.
- W2007704294 cites W2091364404 @default.
- W2007704294 cites W2094975786 @default.
- W2007704294 cites W2095234716 @default.
- W2007704294 cites W2130698887 @default.
- W2007704294 cites W4239765587 @default.
- W2007704294 doi "https://doi.org/10.1016/s0022-0728(78)80027-8" @default.
- W2007704294 hasPublicationYear "1978" @default.
- W2007704294 type Work @default.
- W2007704294 sameAs 2007704294 @default.
- W2007704294 citedByCount "113" @default.
- W2007704294 countsByYear W20077042942012 @default.
- W2007704294 countsByYear W20077042942013 @default.
- W2007704294 countsByYear W20077042942015 @default.
- W2007704294 countsByYear W20077042942016 @default.
- W2007704294 countsByYear W20077042942017 @default.
- W2007704294 countsByYear W20077042942018 @default.
- W2007704294 countsByYear W20077042942019 @default.
- W2007704294 countsByYear W20077042942020 @default.
- W2007704294 countsByYear W20077042942021 @default.
- W2007704294 countsByYear W20077042942022 @default.
- W2007704294 countsByYear W20077042942023 @default.
- W2007704294 crossrefType "journal-article" @default.
- W2007704294 hasAuthorship W2007704294A5012032003 @default.
- W2007704294 hasAuthorship W2007704294A5021161979 @default.
- W2007704294 hasAuthorship W2007704294A5061882933 @default.
- W2007704294 hasConcept C113196181 @default.
- W2007704294 hasConcept C120665830 @default.
- W2007704294 hasConcept C121332964 @default.
- W2007704294 hasConcept C147789679 @default.
- W2007704294 hasConcept C161790260 @default.
- W2007704294 hasConcept C17525397 @default.
- W2007704294 hasConcept C178790620 @default.
- W2007704294 hasConcept C185592680 @default.
- W2007704294 hasConcept C192562407 @default.
- W2007704294 hasConcept C2777869211 @default.
- W2007704294 hasConcept C2779328170 @default.
- W2007704294 hasConcept C32891209 @default.
- W2007704294 hasConcept C52859227 @default.
- W2007704294 hasConcept C555196967 @default.
- W2007704294 hasConcept C62520636 @default.
- W2007704294 hasConceptScore W2007704294C113196181 @default.
- W2007704294 hasConceptScore W2007704294C120665830 @default.
- W2007704294 hasConceptScore W2007704294C121332964 @default.
- W2007704294 hasConceptScore W2007704294C147789679 @default.
- W2007704294 hasConceptScore W2007704294C161790260 @default.
- W2007704294 hasConceptScore W2007704294C17525397 @default.
- W2007704294 hasConceptScore W2007704294C178790620 @default.
- W2007704294 hasConceptScore W2007704294C185592680 @default.
- W2007704294 hasConceptScore W2007704294C192562407 @default.
- W2007704294 hasConceptScore W2007704294C2777869211 @default.
- W2007704294 hasConceptScore W2007704294C2779328170 @default.
- W2007704294 hasConceptScore W2007704294C32891209 @default.
- W2007704294 hasConceptScore W2007704294C52859227 @default.
- W2007704294 hasConceptScore W2007704294C555196967 @default.
- W2007704294 hasConceptScore W2007704294C62520636 @default.
- W2007704294 hasIssue "1" @default.
- W2007704294 hasLocation W20077042941 @default.
- W2007704294 hasOpenAccess W2007704294 @default.
- W2007704294 hasPrimaryLocation W20077042941 @default.
- W2007704294 hasRelatedWork W1969933858 @default.
- W2007704294 hasRelatedWork W2004824042 @default.
- W2007704294 hasRelatedWork W2045999692 @default.
- W2007704294 hasRelatedWork W2154644283 @default.
- W2007704294 hasRelatedWork W2363900421 @default.
- W2007704294 hasRelatedWork W2391757924 @default.
- W2007704294 hasRelatedWork W2899084033 @default.
- W2007704294 hasRelatedWork W2950194614 @default.
- W2007704294 hasRelatedWork W2953181567 @default.
- W2007704294 hasRelatedWork W3187002209 @default.
- W2007704294 hasVolume "89" @default.
- W2007704294 isParatext "false" @default.
- W2007704294 isRetracted "false" @default.
- W2007704294 magId "2007704294" @default.
- W2007704294 workType "article" @default.