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- W2007718084 abstract "The adsorption of N-vinyl-2-pyrrolidone (NV2P) or the monomer of polyvinylpyrrolidone (PVP) at the mercury/solution interface was examined by means of differential capacity vs. potential relations (C-E curves). The usual C-E curve obtained in 1 N sulfuric acid was similar to that of the saturated aliphatic compounds. However, in 1 N sodium sulfate or sodium hydroxide potential dependence of Cmin (minimum differential capacity) was observed as a result of π-electron interaction of adsorbed molecules. The adsorption behavior in 1 N sulfuric acid followed the Langmuir isotherm. The peculiar behavior in 1 N sodium sulfate or sodium hydroxide was explained by means of the Frumkin isotherm with the potential dependence of interaction constant (g), which varied linearly with potential in a range more negative than ca. −0.6 V (SCE) in contrast to nearly constant values in a more positive range. At a relatively high bulk concentration, there was a slight deviation from the Frumkin isotherm and the standard free en..." @default.
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- W2007718084 date "1972-11-01" @default.
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- W2007718084 title "Adsorption of<i>N</i>-Vinyl-2-pyrrolidone at the Mercury/Solution Interface" @default.
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- W2007718084 doi "https://doi.org/10.1246/bcsj.45.3236" @default.
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