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• W2007718105 abstract "Abstract The use of nuclear relaxation as a tool to determine metal-nucleus distances in paramagnetic macromolecules is critically assessed. Calculations of the time dependence of nuclear magnetization in different relaxation experiments, and of nuclear Overhauser effects, were performed on a series of test systems, including cases of chemical exchange. A striking experimental observation has been rationalized on the basis of these calculations. It is concluded that non-selective experiments are the most appropriate to determine metal-nucleus distances in metalloproteins under all conditions." @default.
• W2007718105 created "2016-06-24" @default.
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• W2007718105 date "1998-07-01" @default.
• W2007718105 modified "2023-09-27" @default.
• W2007718105 title "Selective versus non-selective T1 experiments to determine metal-nucleus distances in paramagnetic metalloproteins" @default.
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• W2007718105 doi "https://doi.org/10.1016/s0020-1693(97)06140-9" @default.
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